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Continuous monitoring of soil nitrate levels is essential for effective soil nutrient management. However, limited soil pore water at low soil water content levels hinders miniaturized soil sensor surfaces from efficiently interacting with nutrient ions. To address this, we introduce a nanofibrous mat designed to enhance nitrate detection by increasing connectivity between miniature sensors and the soil solution. Composed of polysulfone, polymethylmethacrylate, and polyvinyl alcohol, this mat is fabricated using electrospinning and electrospray methods to balance water absorbency, mechanical durability, and ease of manufacturing. When wrapped around an ion-selective electrode-based nitrate sensor, the mat improves access to soil pore water, acts as a filter, prevents direct sensor-soil particle contact, and reduces the impact of soil particle surface charges on sensor measurements. Continuous nitrate monitoring with both mat-wrapped and bare sensors was conducted in controlled and field environments. Linear regression analysis indicates that the mat-wrapped sensor has a stronger correlation with conventional salt extract methods for measuring soil nitrate levels. T-tests confirm statistically significant differences between sensor measurements and the salt extraction method. Additionally, Bland-Altman analysis reveals that mat-wrapping reduces mean bias and narrows the limits of agreement, demonstrating improved agreement with the conventional method. Notably, the mat-wrapped sensor performs consistently across varying soil moisture conditions. These findings suggest that the water-absorbing mat improves the ability of the sensor to monitor nitrate continuously by accommodating varying soil moisture levels over time, making the mat-wrapped soil nitrate sensor a viable improvement for in-field measurements of soil solution chemistry. 

Reactive nitrogen (Nr) is an essential nutrient to life on earth, but its mismanagement in waste has emerged as a major problem in water pollution to our ecosystems, causing severe eutrophication and health concerns. Sustainably recovering Nr [such as nitrate (NO3−)–N] and converting it into ammonia (NH3) could mitigate the environmental impacts of Nr, while reducing the NH3 demand from the carbon-intensive Haber–Bosch process. In this work, high-performance NO3−-to-NH3 conversion was achieved in a scalable, versatile, and cost-effective membrane-free alkaline electrolyzer (MFAEL): a remarkable NH3partial current density of 4.22 ± 0.25 A cm−2 with a faradaic efficiency of 84.5 ± 4.9%. The unique configuration of MFAEL allows for the continuous production of pure NH3-based chemicals (NH3 solution and solid NH4HCO3) without the need for additional separation procedures. A comprehensive techno-economic analysis (TEA) revealed the economic competitiveness of upcycling waste N from dilute sources by combining NO3− reduction in MFAEL and a low-energy cost electrodialysis process for efficient NO3− concentration. In addition, pairing NO3− reduction with the oxidation of organic Nr compounds in MFAEL enables the convergent transformation of N–O and C–N bonds into NH3 as the sole N-containing product. Such an electricity-driven process offers an economically viable solution to the growing trend of regional and seasonal Nr buildup and increasing demand for sustainable NH3 with a reduced carbon footprint. 

Nitrogen (N) is an essential but generally limiting nutrient for biological systems. Development of the Haber-Bosch industrial process for ammonia synthesis helped to relieve N limitation of agricultural production, fueling the Green Revolution and reducing hunger. However, the massive use of industrial N fertilizer has doubled the N moving through the global N cycle with dramatic environmental consequences that threaten planetary health. Thus, there is an urgent need to reduce losses of reactive N from agriculture, while ensuring sufficient N inputs for food security. Here we review current knowledge related to N use efficiency (NUE) in agriculture and identify research opportunities in the areas of agronomy, plant breeding, biological N fixation (BNF), soil N cycling, and modeling to achieve responsible, sustainable use of N in agriculture. Amongst these opportunities, improved agricultural practices that synchronize crop N demand with soil N availability are low-hanging fruit. Crop breeding that targets root and shoot physiological processes will likely increase N uptake and utilization of soil N, while breeding for BNF effectiveness in legumes will enhance overall system NUE. Likewise, engineering of novel N-fixing symbioses in non-legumes could reduce the need for chemical fertilizers in agroecosystems but is a much longer-term goal. The use of simulation modeling to conceptualize the complex, interwoven processes that affect agroecosystem NUE, along with multi-objective optimization, will also accelerate NUE gains.